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Tailoring the separation selectivity of metal complexes and organometallic compounds resolved by capillary electrophoresis using auxiliary separation processes
Author(s) -
Boyce Mary C.,
Haddad Paul R.
Publication year - 2003
Publication title -
electrophoresis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.666
H-Index - 158
eISSN - 1522-2683
pISSN - 0173-0835
DOI - 10.1002/elps.200305423
Subject(s) - micellar electrokinetic chromatography , capillary electrophoresis , selectivity , electrokinetic phenomena , chemistry , chromatography , electrophoresis , separation method , metal , organic chemistry , catalysis
Abstract The use of auxiliary separation mechanisms to manipulate the separation selectivity of metal complexes and organometallic species is reviewed. Auxiliary separation mechanisms included in the review are micellar electrokinetic capillary chromatography, ion‐pairing and ion‐exchange electrokinetic chromatography. This paper discusses how these secondary mechanisms can be effectively employed to tailor separation selectivity.