Premium
A theoretical approach to chiral capillary electrophoresis with some practical implications
Author(s) -
Wren Stephen A. C.,
Rowe Raymond C.,
Payne Robin S.
Publication year - 1994
Publication title -
electrophoresis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.666
H-Index - 158
eISSN - 1522-2683
pISSN - 0173-0835
DOI - 10.1002/elps.11501501108
Subject(s) - capillary electrophoresis , chromatography , electrophoresis , capillary action , chemistry , physics , thermodynamics
A simple model has been proposed which explains enantiomeric resolution in capillary electrophoresis in terms of differential interactions with a chiral selector and differential migration of the two enantiomer‐chiral selector complexes. The equations derived allow predictions to be made and there is good support for the model in literature data.