Premium
A quantitative theory of the stern electric double layer
Author(s) -
Michov Budin M.
Publication year - 1988
Publication title -
electrophoresis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.666
H-Index - 158
eISSN - 1522-2683
pISSN - 0173-0835
DOI - 10.1002/elps.1150090410
Subject(s) - stern , radius , atmosphere (unit) , electrokinetic phenomena , ion , double layer (biology) , layer (electronics) , ionic bonding , physics , ionic radius , atomic physics , chemistry , materials science , thermodynamics , nanotechnology , quantum mechanics , computer science , geology , oceanography , computer security
A quantitative theory of the Stern electric double layer is suggested. It is based on the view that every ion possesses a geometrical and an electrokinetic radius, that the ionic atmosphere begins from the geometrical one, and that the difference between these radii is the Stern quantity Δ. The equations of the mentioned radii and the quantity Δ are established and the values of the different potentials characterizing an ion and its ionic atmosphere are determined.