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Electrophoretic transport equations: Electrophoretic models based on migration only and their interrelationships
Author(s) -
Thormann Wolfgang,
Mosher Richard A.
Publication year - 1985
Publication title -
electrophoresis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.666
H-Index - 158
eISSN - 1522-2683
pISSN - 0173-0835
DOI - 10.1002/elps.1150060902
Subject(s) - electromigration , electrophoresis , boundary (topology) , function (biology) , current (fluid) , chemistry , statistical physics , thermodynamics , physics , mathematical analysis , chromatography , mathematics , biology , quantum mechanics , evolutionary biology
The general equations which describe the electrophoretic transport of components in solution are restated using Newman's general concept of mobilities. A concise derivation of the moving boundary equation and the regulating function ω from the continuity equation is presented. Various other regulating principles across moving and stationary boundaries are also discussed, which permits a review of the features and interrelationshpis of the electrophoretic models based on electromigration only. The effect of considering an interactive (dissociating) solvent on the mathematical treatment is discussed.