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Electrocatalysis of Cu−MOF/Graphene Composite and its Sensing Application for Electrochemical Simultaneous Determination of Dopamine and Paracetamol
Author(s) -
Ma Baolong,
Guo Hao,
Wang Mingyue,
Li Li,
Jia Xueyan,
Chen Huiqin,
Xue Rui,
Yang Wu
Publication year - 2019
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201800890
Subject(s) - graphene , electrocatalyst , electrochemistry , dopamine , electrochemical gas sensor , selectivity , nanocomposite , electrode , materials science , oxide , composite number , catalysis , nanometre , chemical engineering , detection limit , specific surface area , nanotechnology , chemistry , chromatography , composite material , organic chemistry , metallurgy , neuroscience , engineering , biology
A nanocomposite of HKUST‐1 (MOF) and electroreduction graphene oxide (ERGO) is prepared and applied as an electrochemical sensor for the simultaneous determination of paracetamol and dopamine by means of one‐step electrodeposition. The MOF/ERGO composite displays excellent electrochemical catalytic activities towards the paracetamol and dopamine, which is attributed to the synergistic effect of big surface area, porosity and high electrocataytic activity of the MOF and good conductivity of ERGO. The modified electrode could be applied to determine simultaneously paracetamol and dopamine in biochemical samples with wide linear ranges (0.2 μM to 160 μM for paracetamol and 0.2 μM to 300 μM for dopamine) and low detection limits (0.016 μM for paracetamol and 0.013 μM for dopamine). Meanwhile, the proposed sensor still displays high sensitivity, good selectivity and excellent stability.