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Iso Points in Electrochemistry. Classification and Verification by Experiment and Theory
Author(s) -
Skitał Piotr M.,
Sanecki Przemysław T.,
Saletnik Dorota
Publication year - 2018
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201800143
Subject(s) - thiourea , electrochemistry , context (archaeology) , interpretation (philosophy) , chemistry , point (geometry) , computational chemistry , mathematics , materials science , computer science , electrode , organic chemistry , geometry , geology , paleontology , programming language
The experimental examples of occurrence of isoalpha points ( iap ) in electroreduction of Cu 2+ , Tl + , Zn 2+ in the presence of 1,3‐dimethyl‐2‐thiourea have been presented. The theoretical ECE and EE model examples of iap and isopotential point ( ipp ) as well as mixed iap / ipp isopoints are discussed in the context of their similarities and differences. Novel extended interpretation of ipp points in electrochemistry, based on concentration profiles approach, was also introduced.