Electrocatalytic Oxidation of Carbohydrates Mediated by Nitroxyl Radical‐modified Electrodes in Aqueous Solution | Zendy

Ono Tetsuya | Zendy; Sato Katsuhiko | Zendy; Shimizu Syunki | Zendy; Yoshida Kentaro | Zendy; Dairaku Takenori | Zendy; Suzuki Yasuhiro | Zendy; Kashiwagi Yoshitomo | Zendy

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Electrocatalytic Oxidation of Carbohydrates Mediated by Nitroxyl Radical‐modified Electrodes in Aqueous Solution

Author(s) -

Ono Tetsuya,

Sato Katsuhiko,

Shimizu Syunki,

Yoshida Kentaro,

Dairaku Takenori,

Suzuki Yasuhiro,

Kashiwagi Yoshitomo

Publication year - 2018

Publication title -

electroanalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.574

H-Index - 128

eISSN - 1521-4109

pISSN - 1040-0397

DOI - 10.1002/elan.201700545

Subject(s) - nitroxyl , aqueous solution , chemistry , electrochemistry , electrode , cyclic voltammetry , buffer solution , inorganic chemistry , phosphate buffered saline , electrocatalyst , polymerization , glassy carbon , chemically modified electrode , pyrrole , working electrode , polymer chemistry , organic chemistry , polymer , chromatography

The electrocatalytic activity of a 2,2,6,6‐tetramethylpipridine‐ N ‐oxyl (TEMPO)‐modified electrode toward the oxidation of carbohydrates in phosphate buffer solution was investigated under neutral aqueous solution conditions at 25 °C. The modified electrode was prepared on the surface of a glassy carbon electrode by the electrochemical polymerization of a TEMPO precursor containing a pyrrole side chain. Cyclic voltammetric studies showed that the anodic peak current increased with the concentration of carbohydrates in a dose‐dependent manner.

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