Premium
Design of Electrochemically Modified fMWCNT‐pencil Graphite Electrode Decorated with Cu and Ag Nanofilm and its Electrocatalytic Behavior Towards Imazethapyr
Author(s) -
Khan Imran,
Pandit Umar J.,
Limaye Sudhir N.
Publication year - 2017
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201700128
Subject(s) - materials science , cyclic voltammetry , dielectric spectroscopy , electrode , electrochemistry , horizontal scan rate , scanning electron microscope , transmission electron microscopy , graphite , electrochemical gas sensor , analytical chemistry (journal) , chemical engineering , nuclear chemistry , nanotechnology , chemistry , composite material , chromatography , engineering
Herein, a facile procedure was developed for designing an electrochemical sensor based on pencil graphite electrode modified with electrochemically synthesized silver and copper nanoparticles (AgNP and CuNP) supported on functionalized multiwalled carbon nanotubes ( f MWCNTs). The electrochemical and morphological characterization was carried out by cyclic voltammetry, Electrochemical Impedance Spectroscopy, Powder X‐ray diffraction, Field Emission Scanning Electron Microscopy, Transmission electron microscopy and Atomic Force Microscopy. The designed sensor exhibited electrocatalytic behavior towards the reduction of Imazethapyr. Results indicates the combination of AgNPs, CuNPs and f MWCNTs on PGE produced remarkable enhancement in electrocatalytic and sensing properties. Various electro‐kinetic parameters like R ct , k app , n, α, E 0 , k 0 , Γ, D and k have been evaluated by CV, impedance and Chronoamperometric studies. The electrochemical performance was improved by optimizing the effect of pH, scan rate, amount of f MWCNTs and deposition parameters of AgNP and CuNP. The sensor was efficaciously applied for determination of Imazethapyr and exhibited a linear correlation in the concentration range of 0.01–5.0 μg mL −1 with low detection limits, 0.159 ng mL −1 using AdSWV. The fabricated sensor exhibited good accuracy, acceptable stability and high efficacy for quantitative determination of Imazethapyr in real samples with notable recoveries ranging from 98 % to 100.2 %.