Premium
Highly Sensitive Hydrazine Sensor Based on Co(OH) 2 Nanoflakes Electrochemically Deposited on MWCNTs
Author(s) -
Kohila rani Karuppasamy,
Devasenathipathy Rajkumar,
Wang SeaFue,
Subramanian K. Sundara
Publication year - 2017
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201600674
Subject(s) - cobalt hydroxide , materials science , hydrazine (antidepressant) , carbon nanotube , x ray photoelectron spectroscopy , nanocomposite , electrode , detection limit , electrochemistry , electrochemical gas sensor , electrocatalyst , scanning electron microscope , cobalt , nuclear chemistry , inorganic chemistry , chemical engineering , analytical chemistry (journal) , nanotechnology , chemistry , composite material , organic chemistry , metallurgy , chromatography , engineering
We delineate the electrochemical preparation of cobalt hydroxide nanoflakes Co(OH) 2 NFs on multi‐walled carbon nanotubes (MWCNTs) by potentiostatic methods. The preparation was done on the surface of glassy carbon electrode (GCE). The prepared nanocomposite was characterized by field emission scanning electron microscopy (FESEM), X‐ray diffraction spectroscopy (XRD) and X‐ray photo electron spectroscopy (XPS). The resulting f‐ MWCNTs/Co(OH) 2 NFs modified GCE exhibits a good electrocatalytic activity for the oxidation of hydrazine in terms of decreasing over potential and increasing peak current. The modified electrode holds good in the linear range from 0.5 to 15.5 μM with limit of detection as 87.5 nM. The sensitivity of our modified electrode is calculated to be 5733 μA/mM cm‐2. Remarkably, the obtained LOD value of our sensor is very lower compared to the recommended concentration of hydrazine in water by World health organization (WHO) and Environmental protective agency (EPA). The modified electrode detects hydrazine selectively even in the presence of common interferants. Various water samples were chosen to study the practical feasibility of our sensor. The sensor also exhibited an appreciable stability, repeatability and reproducibility.