Electron Transfer Rates in an Adsorbed C 60 ‐Porphyrin Dyad | Zendy

Fortgang Philippe | Zendy; Urbani Maxence | Zendy; Holler Michel | Zendy; Nierengarten JeanFrançois | Zendy; Moreau Alain | Zendy; DelavauxNicot Béatrice | Zendy; Maisonhaute Emmanuel | Zendy

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Electron Transfer Rates in an Adsorbed C 60 ‐Porphyrin Dyad

Author(s) -

Fortgang Philippe,

Urbani Maxence,

Holler Michel,

Nierengarten JeanFrançois,

Moreau Alain,

DelavauxNicot Béatrice,

Maisonhaute Emmanuel

Publication year - 2015

Publication title -

electroanalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.574

H-Index - 128

eISSN - 1521-4109

pISSN - 1040-0397

DOI - 10.1002/elan.201400618

Subject(s) - porphyrin , electron transfer , ultramicroelectrode , photochemistry , redox , dyad , chemistry , molecule , electrochemistry , electrode , materials science , inorganic chemistry , cyclic voltammetry , physics , organic chemistry , acoustics

Association of C 60 and porphyrin entities to build light harvesting systems is a promising alternative for future photovoltaic devices. Herein, we determine the electron transfer rates in a C 60 ‐porphyrin dyad anchored onto a gold ultramicroelectrode via the porphyrin core. Similar rates are observed for both redox entities, suggesting a tilt of the molecules allowing an efficient through‐space communication between C 60 and the electrode.

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