Iodine Sensing by AgI and AgI 1− x  Cl  x | Zendy

Clinsha P. C. | Zendy; Gnanasekar K. I. | Zendy; Jayaraman V. | Zendy; Gnanasekaran T. | Zendy

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Iodine Sensing by AgI and AgI 1− x Cl x

Author(s) -

Clinsha P. C.,

Gnanasekar K. I.,

Jayaraman V.,

Gnanasekaran T.

Publication year - 2014

Publication title -

electroanalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.574

H-Index - 128

eISSN - 1521-4109

pISSN - 1040-0397

DOI - 10.1002/elan.201400248

Subject(s) - iodine , potentiometric titration , electrochemistry , analytical chemistry (journal) , chemistry , conductivity , inorganic chemistry , materials science , electrode , chromatography , organic chemistry

Compositions of nominal formula, AgI 1− x Cl x ( x =0–0.25) were prepared by soft chemical method. The synthesized compositions were characterized by various physicochemical techniques. The studies revealed the formation of solid solution of AgCl in AgI up to 5 mol %. The composition AgI 0.95 Cl 0.05 exhibited marginally higher conductivity than AgI. Electrochemical sensors were assembled using AgI and AgI 0.95 Cl 0.05 . Iodine sensing properties of these two potentiometric sensors were elucidated. Preliminary results show that I 2 can be sensed down to ∼10 vppm.

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