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Electrochemical Deposition of Nickel Nanoparticles on Reduced Graphene Oxide Film for Nonenzymatic Glucose Sensing
Author(s) -
Zhang Yue,
Xiao Xianping,
Sun Yujing,
Shi Yan,
Dai Haichao,
Ni Pengjuan,
Hu Jingting,
Li Zhuang,
Song Yonghai,
Wang Li
Publication year - 2013
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201200479
Subject(s) - graphene , materials science , electrochemistry , nanomaterials , oxide , nanoparticle , detection limit , chemical engineering , nickel , electrode , inorganic chemistry , nuclear chemistry , nanotechnology , chemistry , metallurgy , chromatography , engineering
Electrochemical reduction and electrodeposition are two effective methods for the preparation of new nanomaterials for electrochemical sensing. In this work, the reduced graphene oxide‐nickel nanoparticles composite (RGO‐NiNPs) was synthesized using both methods mentioned above. The fabrication process was simple and easily performed. Then, the RGO‐NiNPs composite was characterized by SEM, EDS, and XRD. Furthermore, for the strong catalytic ability of the high‐valent oxyhydroxide species (NiOOH) formed in alkaline media, the composite was used as the matrix for nonenzymatic detection of glucose. Comparing with NiNPs modified glassy carbon electrode (NiNPs/GCE), the RGO‐NiNPs/GCE showed better sensitivity and stability. A low detection limit of 0.1 µM with a wide linear range from 2 µM to 2.1 mM ( R =0.996) was obtained.