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Oxidation of 6‐Benzylaminopurine‐Copper(I) Complex on Pencil Graphite Electrode
Author(s) -
Serrano Núria,
Alberich Arístides,
Trnkova Libuse
Publication year - 2012
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201100702
Subject(s) - linear sweep voltammetry , copper , voltammetry , chemistry , cyclic voltammetry , electrode , adsorptive stripping voltammetry , stoichiometry , inorganic chemistry , analytical chemistry (journal) , electrochemistry , chromatography , organic chemistry
A voltammetric study of the 6‐benzylaminopurine (BAP)/Cu(I) system is performed. BAP is an adenine‐type cytokinin that elicits cell division in plants and presents antitumor activity when forming complexes with different transition metal ions as copper(I). In the frame of this research field, an analysis of linear sweep voltammetry (LSV), adsorptive stripping voltammetry (AdSV), and elimination voltammetry with linear scan (EVLS) data obtained with a pencil graphite electrode (PeGE), allows us to propose the stoichiometry of the possible complexes formed and the mechanism for total electrode reactions of the BAP/Cu(I) system.