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Sensitive Hydrazine Detection Using a Porous Mn 2 O 3 Nanofibers‐Based Sensor
Author(s) -
Ding Yu,
Hou Changjun,
Li Baikun,
Lei Yu
Publication year - 2011
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201000660
Subject(s) - hydrazine (antidepressant) , nanofiber , calcination , detection limit , electrospinning , materials science , selectivity , linear range , amperometry , porosity , reproducibility , chemical engineering , nanotechnology , nuclear chemistry , chromatography , electrochemistry , chemistry , electrode , polymer , catalysis , organic chemistry , composite material , engineering
Following a facile two‐step synthetic route (electrospinning and subsequent calcination), highly porous Mn 2 O 3 nanofibers (Ø 105 nm) were fabricated. The as‐prepared Mn 2 O 3 nanofibers were applied to construct an amperometric sensor for hydrazine detection in neutral phosphate buffer. The developed hydrazine sensor showed a fast response time (within 5 s), a wide linear range up to 644 µM, a high sensitivity of 474 µA mM −1 cm −2 , a good limit of detection of 0.3 µM ( S / N =3) as well as good reproducibility and selectivity. These results demonstrate that Mn 2 O 3 nanofibers have great potential in the application of hydrazine detection.

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