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Stereoselective Interaction between DNA and Stable Chiral Surfaces Modified with 1,2‐Diphenylethylenediamine Enantiomers
Author(s) -
Wang Lilan,
Fu Yingzi,
Zhou Juan,
Chen Qiao
Publication year - 2011
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.201000476
Subject(s) - quartz crystal microbalance , enantiomer , stereoselectivity , cyclic voltammetry , chirality (physics) , chemistry , adsorption , electrochemistry , dielectric spectroscopy , molecule , crystallography , electrode , stereochemistry , organic chemistry , catalysis , nambu–jona lasinio model , chiral symmetry breaking , physics , quantum mechanics , quark
This work described an interesting phenomenon of the stereoselective adsorption behaviors of DNA on stable chiral surfaces which were modified with 1,2‐diphenylethylenediamine enantiomers on gold electrodes. The modification process and electrochemical characterization of the chiral surfaces were measured by cyclic voltammetry (CV). The stereoselective adsorption behaviors of DNA on the two chiral surfaces were investigated via atomic force microscopy (AFM), CV, electrochemical impedance spectroscopy (EIS) and quartz crystal microbalance (QCM). All results confirmed that ( 1R,2R )‐1,2‐diphenylethylenediamine modified surface had stronger interaction with DNA molecules than ( 1S,2S )‐1,2‐diphenylethylenediamine modified surface, and the chirality of the surfaces created an different effect on the morphology and adsorption quantity of DNA.