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On the Utilization of Boron Doped Diamond Electrode as a Sensor for Parathion and as an Anode for Electrochemical Combustion Of Parathion
Author(s) -
Pedrosa Valber A.,
Miwa Douglas,
Machado Sergio A. S.,
Avaca Luis A.
Publication year - 2006
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.200603561
Subject(s) - parathion , anode , diamond , combustion , electrode , electrochemistry , boron , materials science , chemistry , pesticide , metallurgy , organic chemistry , agronomy , biology
This work proposes the utilization of a boron doped diamond (BDD) electrode as a sensor for pesticides and as well as an anode for electrochemical combustion of Parathion in spiked, pure and natural waters. The square‐wave voltammetry was selected as the electroanalytical technique and the Britton–Robinson buffer as the electrolyte. The electrochemical reduction responses of Parathion were analyzed and compared with those previously obtained using a hanging mercury electrode (HMDE). The detection and quantification limits were calculated from the analytical curves both for BDD and HMDE in Milli‐Q water (2.4 and 7.9 μg L −1 and 3.9 and 12.8 μg L −1 respectively) showing only a slight improvement when used BDD. However, if the application involves polluted natural waters the improvement is accentuated due to the very low adsorption characteristics of BDD, which prevent the fouling of electrode surface by organic pollutants. The BDD was also used as anode for electrochemical remediation of Parathion contamination. In this case, electrolysis was carried out in high positive potential (3.0 V) and lead the electrochemical combustion of Parathion to CO 2 and H 2 O, as measured by the diminishing of total organic carbon in the electrolyte.