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Be(II) Graphite Coated Membrane Sensor Based on a Recently Synthesized Benzo‐9‐Crown‐3 Derivative
Author(s) -
Ganjali Mohammad Reza,
Akbar Vahideh,
Norouzi Parviz,
Moghimi Abolghasem,
Sepehrifard Ali
Publication year - 2005
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.200303169
Subject(s) - ionophore , membrane , detection limit , acetophenone , chemistry , polyvinyl chloride , titration , selectivity , vinyl chloride , metal ions in aqueous solution , inorganic chemistry , alkali metal , derivative (finance) , solvent , chloride , electrode , ion , nuclear chemistry , chromatography , polymer , organic chemistry , biochemistry , economics , financial economics , copolymer , catalysis
A highly sensitive and selective membrane electrode with 9‐crown‐3 derivative (CD) as ionophore, potassium tetrakis‐( p ‐chlorophenyl) borate as anionic additive (KTB), acetophenone (AP) as solvent mediator was prepared and investigated as a Be(II) sensor. The best performance was observed with the membrane having the percent ratio 30% PVC: 8% CD: 6% KTB: 56% Acetophenone. The poly(vinyl chloride) PVC membrane containing 9‐crown‐3 derivative (CD) directly coated on a graphite electrode, shows a Nernstian response for Be(II) ions over a very wide concentration range (1.0×10 −1 −1.0×10 −7 M) with a detection limit of 8.0×10 −8 M (ca. 0.72 ng/mL). It has a fast response time of ca. 20 s and can be used for at least 10 weeks without any major deviation in potential. The proposed sensor exhibits very good selectivity with respect to common alkali, alkaline earth, transition and heavy metal ions. The proposed sensor was used as end point indicator electrode in the titration of Be(II) ions with EDTA. It was also applied to determination of Be(II) in real sample.