Study on Electrochemiluminesce of Ru(bpy 3 ) 2+  Immobilized in a Titania Sol‐Gel Membrane | Zendy

Zhuang Yafeng | Zendy; Ju Huangxian | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Study on Electrochemiluminesce of Ru(bpy 3 ) 2+ Immobilized in a Titania Sol‐Gel Membrane

Author(s) -

Zhuang Yafeng,

Ju Huangxian

Publication year - 2004

Publication title -

electroanalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.574

H-Index - 128

eISSN - 1521-4109

pISSN - 1040-0397

DOI - 10.1002/elan.200302953

Subject(s) - oxalate , chemiluminescence , ruthenium , chemistry , inorganic chemistry , electrochemiluminescence , electrode , glassy carbon , electrochemistry , membrane , nuclear chemistry , cyclic voltammetry , catalysis , chromatography , organic chemistry , biochemistry

The immobilization of tris(2,2′‐bipyridyl)ruthenium(II), Ru(bpy) 3 2+ , at a glassy carbon electrode was achieved by entrapping the Ru(bpy) 3 2+ in a vapor deposited titania sol‐gel membrane. The electrogenerated chemiluminescence (ECL) of the immobilized Ru(bpy) 3 2+ was studied. The Ru(bpy) 3 2+ modified electrode showed a fast ECL response to both oxalate and proline. The ECL intensity was linearly related to concentrations of oxalate and proline over the ranges from 20 to 700 μmol L −1 and 20 to 600 μmol L −1 , respectively. The detection limits for oxalate and proline at 3σ were 5.0 μmol L −1 and 4.0 μmol L −1 , respectively. This electrode possessed good precision and stability for oxalate and proline determinations. The electrogenerated chemiluminescence mechanism of proline system was discussed. This work provided a new way for the immobilization of Ru(bpy) 3 2+ and the application of titania sol‐gel membrane in electrogenerated chemiluminescence.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research