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Determination of standard rate constants for electrochemical irreversible processes from linear sweep voltammograms
Author(s) -
Velasco Jaime González
Publication year - 1997
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.1140091116
Subject(s) - linear sweep voltammetry , detection limit , limit (mathematics) , reaction rate constant , electrochemistry , analytical chemistry (journal) , constant (computer programming) , voltammetry , chemistry , thermodynamics , materials science , physics , electrode , mathematical analysis , mathematics , chromatography , kinetics , cyclic voltammetry , computer science , classical mechanics , programming language
Abstract A new equation has been deduced from which a direct determination of the standard rate constant from linear sweep voltammograms can be made. Some questions related with the detection limit of irreversibility by means of the linear voltammetric method are also discussed.