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Computer modeling of the membrane–solution interface of liquid membrane ion‐selective electrodes
Author(s) -
Vincze Arpad,
Horvai George,
Leermakers Frans A. M.
Publication year - 1995
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.1140070915
Subject(s) - membrane , potentiometric titration , electrode , ion , ion selective electrode , chemistry , salt (chemistry) , interference (communication) , inorganic chemistry , detection limit , analytical chemistry (journal) , chromatography , selectivity , organic chemistry , computer science , computer network , biochemistry , channel (broadcasting) , catalysis
The potentiometric behavior of liquid membrane ion‐selective electrodes with neutral carrier has been qualitatively reproduced by a computer model. Phenomena like Nernstian response, cation and anion interference, detection limit and the effect of lipophilic salt additives could be successfully modeled.