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Square wave voltammetry with arrays of liquid/liquid microinterfaces
Author(s) -
Pereira C. Melo,
Silva Fernando
Publication year - 1994
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.1140061120
Subject(s) - voltammetry , polyester , square wave , square (algebra) , microelectrode , analytical chemistry (journal) , materials science , cyclic voltammetry , dichloroethane , liquid liquid , electrode , ion , chemistry , chromatography , electrochemistry , organic chemistry , composite material , electrical engineering , geometry , mathematics , voltage , catalysis , engineering
Square wave voltammetry (SWV) has been successfully applied to arrays of liquid/liquid (L/L)microinterfaces formed across microholes perforated on a polyester film. The study of CIO 4 − ion transfer from water to 1.2‐dichloroethane (DCE) showed that the experimental parameters E sw , E s , and f are identical to those found for the reversible electron transfer on solid microelectrodes.