Amalgam electrodes: Direct electrochemical generation of cadmium macrocyclic complexes | Zendy

Boudon C. | Zendy; Gisselbrecht J. P. | Zendy; Gross M. | Zendy

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Amalgam electrodes: Direct electrochemical generation of cadmium macrocyclic complexes

Author(s) -

Boudon C.,

Gisselbrecht J. P.,

Gross M.

Publication year - 1992

Publication title -

electroanalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.574

H-Index - 128

eISSN - 1521-4109

pISSN - 1040-0397

DOI - 10.1002/elan.1140040106

Subject(s) - propylene carbonate , electrochemistry , amalgam (chemistry) , chemistry , heteroatom , cadmium , inorganic chemistry , stoichiometry , lewis acids and bases , carbonate , coordination complex , electrode , organic chemistry , metal , catalysis , ring (chemistry)

The electrochemical oxidation of cadmium amalgam was studied in the nonaqueous solvents CH 2 Cl 2 , 1,2‐C 2 H 4 Cl 2 and propylene carbonate. Significant coordination effects were observed between the electrogenerated Cd(II) ions and 18‐membered macromonocyclic ligands, each containing six Lewis bases heteroatoms: 18‐O 6 , 18‐S 6 , 18‐N 2 O 4 , and 18‐N 6 . The stoichiometries and the stabilities of the resulting complexes were determined. These stabilities increase from 18‐O 6 or 18‐S 6 to 18‐N 6 .

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