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Theory of potentiometric stripping analysis in the case of reversible and quasi‐reversible electrode reactions
Author(s) -
Garai Tibor,
Mészáros Lajos,
Bartalits Liliana,
Locatelli Clinio,
Fagioli Francesco
Publication year - 1991
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.1140030913
Subject(s) - potentiometric titration , stripping (fiber) , electrode , chemistry , diffusion , analytical chemistry (journal) , inorganic chemistry , materials science , thermodynamics , chromatography , composite material , physics
The theoretical treatment of potentiometric stripping analysis is presented for the cases of reversible and quasi‐reversible electrode reactions. The experimental results were found to be in good agreement with calculated data. Derivations based on different assumptions (e.g., stripping in stirred solutions, diffusion layer of constant thickness) are compared.