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A thin‐layer electrode cell for fluorescence. Measurements on electrogenerated intermediates
Author(s) -
Compton Richard G.,
Fisher Adrian C.,
Wellington R. Geoffrey
Publication year - 1991
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/elan.1140030105
Subject(s) - luminescence , electrochemiluminescence , photochemistry , electrode , fluorescence , amine gas treating , chemistry , layer (electronics) , ion , tris , radical ion , inorganic chemistry , materials science , optoelectronics , organic chemistry , optics , biochemistry , physics
A new methodology for the study of luminescence from photoexcited electrogenerated species is presented. A suitable optically transparent thin‐layer electrode compatible with fluorescence spectrometer was developed, and this was used to study luminescence from the radical cation of tris(4‐methylphenyl)amine and the radical anion of 9,10‐anthracenedione electrogenerated in situ.