Mechanism of electrochemical oxidation of sulfamerazine at a pyrolytic graphite electrode | Zendy

Goyal R. N. | Zendy; Mathur N. C. | Zendy; Bhargava S. | Zendy

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Mechanism of electrochemical oxidation of sulfamerazine at a pyrolytic graphite electrode

Author(s) -

Goyal R. N.,

Mathur N. C.,

Bhargava S.

Publication year - 1990

Publication title -

electroanalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.574

H-Index - 128

eISSN - 1521-4109

pISSN - 1040-0397

DOI - 10.1002/elan.1140020111

Subject(s) - pyrolytic carbon , coulometry , linear sweep voltammetry , sulfamerazine , cyclic voltammetry , electrochemistry , electrode , chemistry , voltammetry , inorganic chemistry , materials science , organic chemistry , pyrolysis , sulfadiazine , biochemistry , antibiotics

The electrochemical oxidation of sulfamerazine at a pyrolytic graphite electrode was studied in phosphate buffers with a pH ranging from 3.0 to 10.8. The 2 e − , 2H + oxidation of this compound produces an azo product. A possible reaction scheme is proposed on the basis of the results of linear sweep and cyclic voltammetry, coulometry, spectral studies, and product identification.

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