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Intermolecular Dehydrogenative C−H/Si−H Cross‐Coupling for the Synthesis of Arylbenzyl Bis(silanes)
Author(s) -
You Lijun,
Yuan Wei,
He Chuan
Publication year - 2021
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.202100474
Subject(s) - silanes , chemistry , intermolecular force , regioselectivity , iridium , silylation , atom economy , catalysis , organic chemistry , molecule , silane
An iridium‐catalyzed intermolecular dehydrogenative C−H/Si−H cross‐coupling reaction for the synthesis of arylbenzyl bis(silanes) is developed. This hydrosilyl group steered intermolecular C−H silylation process features high chemo‐ and regioselectivity, giving access to a wide range of multi‐functionalized organosilanes in good yields from readily available starting materials with atom economy, efficiency, and environmental benignity.