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Electrochemical Tandem Cyclization of Unsaturated Oximes with Diselenides: A General Approach to Seleno Isoxazolines Derivatives with Quaternary Carbon Center
Author(s) -
Gao Wenchao,
Li Beibei,
Zong Luyi,
Yu Lintao,
Li Xuyang,
Li Qiyang,
Zhang Xu,
Zhang Sheng,
Xu Kun
Publication year - 2021
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.202100294
Subject(s) - chemistry , tandem , quaternary carbon , functional group , electrochemistry , combinatorial chemistry , carbon fibers , organic chemistry , catalysis , enantioselective synthesis , materials science , polymer , electrode , composite number , composite material
Electrochemical oxidative tandem cyclization of unsaturated oximes with diselenides has been developed to provide a general access to seleno isoxazolines containing a quaternary carbon center (35 examples). This novel protocol features with mild reaction conditions (metal‐ and oxidant‐free), good functional group tolerance and promising scalability. Moreover, plausible reaction pathways have been proposed.