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Glycosamine Derivatives through Metal‐Catalyzed C−N Bond Formation on Protected and Unprotected 2‐Iodoglycals
Author(s) -
Malinowski Maciej,
Banoun Camille,
Robichon Morgane,
LubinGermain Nadège,
Ferry Angélique
Publication year - 2021
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.202100221
Subject(s) - chemistry , hydrogenolysis , catalysis , front cover , stereochemistry , copper , nickel , polymer chemistry , organic chemistry , cover (algebra) , mechanical engineering , engineering
The Front Cover shows the developed transformation of 2‐iodoglycals into C2 ‐amidoglycals through a dual nickel/copper catalyzed C–N bond formation. These C2 ‐amidoglycals were successfully post‐functionalized by hydrogenolysis into three d‐mannosamine or d‐talosamine mimics represented along the bridge on the picture. The background picture is one famous site of Cergy‐Pontoise city, named « Axe Majeur », developed by the architect Dani Karavan. The authors of the publication thank the « Fondation de la Maison de la Chimie » for the funding support. More information can be found in the Communication by A. Ferry et al.