New Chiral BINOL‐Based Phosphates for Enantioselective [Au(I)]‐Catalyzed Dearomatization of β‐Naphthols with Allenamides | Zendy

Pedrazzani Riccardo | Zendy; An Juzeng | Zendy; Monari Magda | Zendy; Bandini Marco | Zendy

Premium

New Chiral BINOL‐Based Phosphates for Enantioselective [Au(I)]‐Catalyzed Dearomatization of β‐Naphthols with Allenamides

Author(s) -

Pedrazzani Riccardo,

An Juzeng,

Monari Magda,

Bandini Marco

Publication year - 2021

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.202100166

Subject(s) - enantioselective synthesis , chemistry , stereoselectivity , catalysis , counterion , phosphate , combinatorial chemistry , organic chemistry , organocatalysis , ion

New chiral BINOL‐based phosphate counterions have been synthesized, fully characterized, and employed in the enantioselective gold‐catalyzed dearomatization of β‐naphthols with allenamides. A range of densely functionalized C1‐allylated naphthalenones were realized under mild conditions and high levels of chemo‐, regio‐ and stereoselectivity ( ee up to 95 %).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research