Chiral Molecular Cages Based on Cyclotriveratrylene and Sucrose Units Connected with  p ‐Phenylene Linkers | Zendy

Szyszka Łukasz | Zendy; Cmoch Piotr | Zendy; Górecki Marcin | Zendy; Ceborska Magdalena | Zendy; Potopnyk Mykhaylo A. | Zendy; Jarosz Sławomir | Zendy

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Chiral Molecular Cages Based on Cyclotriveratrylene and Sucrose Units Connected with p ‐Phenylene Linkers

Author(s) -

Szyszka Łukasz,

Cmoch Piotr,

Górecki Marcin,

Ceborska Magdalena,

Potopnyk Mykhaylo A.,

Jarosz Sławomir

Publication year - 2021

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.202001482

Subject(s) - chemistry , diastereomer , phenylene , stereochemistry , crystallography , crystal structure , absolute configuration , organic chemistry , polymer

Four diastereomeric molecular cages based on cyclotriveratrylene (CTV) and sucrose scaffolds, connected via p ‐phenylene linkers, were synthesized in a few steps synthesis. The absolute configuration of these diastereoisomers was determined by advanced NMR and ECD spectroscopies supported by DFT calculations. The X‐Ray crystal structure of P ‐4 b cage gave an insight into its unique structure. The binding properties of P ‐4 a and M ‐4 a cages towards small ammonium guests (1‐methylpyridinium and 1,3‐dimethylimidazolium salts) were investigated.

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