Synthesis of Anemoclemosides A and B, Two Saponins Isolated from  Anemoclema glaucifolium | Zendy

Bouillon Marc E. | Zendy; Bertocco Katia | Zendy; Bischoff Laura | Zendy; Buri Michelle | Zendy; Davies Lucy R. | Zendy; Wilkinson Elizabeth J. | Zendy; Lahmann Martina | Zendy

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Synthesis of Anemoclemosides A and B, Two Saponins Isolated from Anemoclema glaucifolium

Author(s) -

Bouillon Marc E.,

Bertocco Katia,

Bischoff Laura,

Buri Michelle,

Davies Lucy R.,

Wilkinson Elizabeth J.,

Lahmann Martina

Publication year - 2020

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.202001317

Subject(s) - chemistry , stereochemistry , rhamnose , glycosidic bond , saponin , arabinose , triterpene , ranunculaceae , acetal , glycoside , polysaccharide , organic chemistry , botany , xylose , enzyme , medicine , alternative medicine , pathology , fermentation , biology

Steroidal and triterpenoid saponins are attractive for their wide‐ranging pharmacological properties. The triterpenoid saponins Anemoclemoside A and B are root constituents of the Chinese folk medicinal plant Anemoclema glaucifolium (Ranunculaceae). Both compounds feature an unusual cyclic acetal linkage to the carbohydrate l ‐arabinose in its open chain form rather than the typical glycosidic bond present in normal saponins. The straightforward and scalable syntheses of both saponins starting from l ‐arabinose as well as l ‐lyxose and l ‐rhamnose are described.

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