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Recent Advances in the Chemistry of Isocyanides with Activated Methylene Group
Author(s) -
Efimov Ilya V.,
Kulikova Larisa N.,
Zhilyaev Dmitry I.,
Voskressensky Leonid G.
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.202000890
Subject(s) - chemistry , methylene , cycloaddition , catalysis , organic chemistry , isocyanide , medicinal chemistry , combinatorial chemistry
This review is devoted to the recent advances in the chemistry of methylene isocyanides with C=C, C≡C, C=O, and C=N bonds. In this paper, we show a variety of [3+2] cycloaddition reactions for isocyanides, carried out both under catalytic and non‐catalytic conditions. In addition, we also focused on diastereo‐ and enantioselectivity data.