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Cover Feature: Visible Light‐Induced Radical Iodoperfluoroalkylation of Unactivated Olefins Cooperatively Catalyzed by Enamines and Amines (Eur. J. Org. Chem. 25/2020)
Author(s) -
Yajima Tomoko,
Murase Mao,
Ofuji Yu
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.202000883
Subject(s) - chemistry , cover (algebra) , pyrrolidine , catalysis , enamine , iodide , amine gas treating , photochemistry , feature (linguistics) , polymer chemistry , visible spectrum , medicinal chemistry , organic chemistry , combinatorial chemistry , mechanical engineering , linguistics , philosophy , engineering , physics , optoelectronics
The Cover Feature shows visible light induced radical perfluoroalkylation catalyzed by amine and enamine. Various unactivated alkenes and alkynes are reacted with perfluoroalkyl iodide to give corresponding iodopefluoroalkylation product in the presence of catalytic amount of diphenylacetaldehyde and pyrrolidine under photoirradiation using 23W CFL lamp. We thank Aya Nishikawa for drawing such a cute picture. More information can be found in the Communication by T. Yajima et al.