Photocatalytic Synthesis of 3‐Sulfanyl‐ and 1,3‐Bis(sulfanyl)indolizines Mediated by Visible Light | Zendy

Penteado Filipe | Zendy; Gomes Caroline S. | Zendy; Monzon Loana I. | Zendy; Perin Gelson | Zendy; Silveira Claudio C. | Zendy; Lenardão Eder J. | Zendy

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Photocatalytic Synthesis of 3‐Sulfanyl‐ and 1,3‐Bis(sulfanyl)indolizines Mediated by Visible Light

Author(s) -

Penteado Filipe,

Gomes Caroline S.,

Monzon Loana I.,

Perin Gelson,

Silveira Claudio C.,

Lenardão Eder J.

Publication year - 2020

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.202000162

Subject(s) - sulfanyl , chemistry , photocatalysis , photochemistry , visible spectrum , indolizine , catalysis , metal , combinatorial chemistry , medicinal chemistry , organic chemistry , physics , optoelectronics

A metal‐free method for the synthesis of 3‐sulfanyl indolizines from thiols and 2‐arylindolizines, is reported. The reaction is mediated by eosin Y under blue LED light irradiation and uses atmospheric oxygen as oxidant. By the use of a catalytic amount of I 2 , the corresponding 1,3‐bis‐sulfanyl indolizines are obtained, in good yields.

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