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Ruthenium‐Catalyzed ortho ‐Alkenylation of Aroylgermanes
Author(s) -
Wang Hai,
Yuan Yang,
Zhang Youcan,
Franke Robert,
Wu XiaoFeng
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.202000062
Subject(s) - ruthenium , chemistry , catalysis , selectivity , functional group , combinatorial chemistry , medicinal chemistry , group (periodic table) , photochemistry , organic chemistry , polymer
In this communication, a ruthenium‐catalyzed ortho ‐alkenylation of acylgermanes with electron‐deficient alkenes through direct C–H bond activation has been developed. With acylgermane as the directing group, this method provides a straightforward access to diverse acylgermanes derivatives with good functional group tolerance and site‐selectivity under mild reaction conditions.