Diboron‐Mediated Rhodium‐Catalysed Transfer Hydrogenation of Alkenes and Carbonyls | Zendy

Lin Xiao | Zendy; Wang Yuhan | Zendy; Hu Yan | Zendy; Zhu Wanjiang | Zendy; Dou Xiaowei | Zendy

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Diboron‐Mediated Rhodium‐Catalysed Transfer Hydrogenation of Alkenes and Carbonyls

Author(s) -

Lin Xiao,

Wang Yuhan,

Hu Yan,

Zhu Wanjiang,

Dou Xiaowei

Publication year - 2020

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.202000049

Subject(s) - rhodium , chemistry , catalysis , transfer hydrogenation , hydrogen , organic chemistry , functional group , alkene , combinatorial chemistry , medicinal chemistry , ruthenium , polymer

A diboron‐mediated rhodium‐catalysed transfer hydrogenation system using water as the hydrogen donor is developed. In addition to a series of alkenes with good functional group tolerance, this rhodium‐based catalytic system also effectively reduces aldehydes and ketones. A plausible mechanism involving the Rh I ‐catalysed hydrogen generation and Rh 0 ‐catalysed hydrogenation is proposed for the reaction.

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