Premium Visible Light‐Induced Radical Iodoperfluoroalkylation of Unactivated Olefins Cooperatively Catalyzed by Enamines and AminesPremium
Author(s)
Yajima Tomoko,
Murase Mao,
Ofuji Yu
Publication year2020
Publication title
european journal of organic chemistry
Resource typeJournals
PublisherWiley
Fluoro‐organic compounds feature prominently in functional materials and in the pharmaceutical and agrochemical industries. Herein, we report a visible light‐induced atom transfer radical addition of perfluoroalkyl iodide to alkenes/alkynes in the presence of aldehydes and amines. The metal‐free process requires mild reaction conditions and enables iodoperfluoroalkylation. The reaction proceeds via the cooperative action of an enamine and amine.
Subject(s)amine gas treating , atom transfer radical polymerization , catalysis , chemistry , combinatorial chemistry , copolymer , enamine , enantioselective synthesis , iodide , organic chemistry , organocatalysis , photochemistry , polymer , radical
Language(s)English
SCImago Journal Rank0.825
H-Index155
eISSN1099-0690
pISSN1434-193X
DOI10.1002/ejoc.201901896
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