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Manganese‐Catalyzed One‐Pot Conversion of Nitroarenes into N ‐Methylarylamines Using Methanol
Author(s) -
ReedBerendt Benjamin G.,
Mast Nicolas,
Morrill Louis C.
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201901854
Subject(s) - chemistry , manganese , methanol , pincer movement , catalysis , transfer hydrogenation , combinatorial chemistry , organic chemistry , ruthenium
A manganese‐catalyzed one‐pot conversion of nitroarenes into N ‐methylarylamines has been developed. This transfer hydrogenation method employs a well‐defined bench stable Mn PN 3 P pincer precatalyst in combination with methanol as both the reductant and the C1 source. A selection of commercially available nitroarenes was converted into N ‐methylarylamines in synthetically useful yields.
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