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Synthetic Routes to Extended Polyconjugated Structures
Author(s) -
Punzi Angela,
Babudri Francesco,
Farinola Gianluca M.
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201901847
Subject(s) - stille reaction , chemistry , conjugated system , palladium , coupling reaction , molecule , polymer , combinatorial chemistry , surface modification , small molecule , organic chemistry , catalysis , biochemistry
This review covers our recent contribution on the synthesis of extended polyconjugated compounds, such as conjugated polymers and small molecules. The synthetic strategies developed in our research group are mainly based on palladium‐catalyzed cross‐coupling reactions involving a variety of organometallic intermediates as well as on direct arylation reactions via C–H functionalization. This report is organized according to the synthetic methods used (coupling of unsaturated organosilanes, Suzuki–Miyaura cross‐coupling, Stille cross‐coupling, direct arylation) and the typologies of the structures synthesized (polymers, small molecules).