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Cover Feature: Mono‐ and Tri‐Functionalization of Trimethylresorcin[4]arenes (Eur. J. Org. Chem. 1/2020)
Author(s) -
Loose Dirk,
Aniol Alexandra,
Feigel Martin,
Röhling Sebastian,
Dyker Gerald
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201901799
Subject(s) - chemistry , resorcinarene , supramolecular chemistry , cover (algebra) , halogenation , surface modification , yield (engineering) , combinatorial chemistry , molecule , feature (linguistics) , organic chemistry , computational chemistry , thermodynamics , mechanical engineering , engineering , linguistics , physics , philosophy
The Cover Feature shows the simplified three‐step synthesis of mono‐ and tri‐functionalized resorcin[4]arenes, with the central structure as one target molecule. Circumventing the first step statistical product mixture – illustrated in the background – by utilizing the significant different product solubilities, led to easy manageable binary mixtures. Complementary regiospecific conditions for the bromination of the trimethyl‐resorcinarene were applied, resulting in high‐yield syntheses of potential building blocks for supramolecular chemistry. More information can be found in the Full Paper by G. Dyker et al.