Visible‐Light‐Induced Metal‐Free Trifluoromethylselenolation of Electron‐Rich Heteroarenes Using the Nucleophilic [Me 4 N][SeCF 3 ] Reagent | Zendy

De ZordoBanliat Arnaud | Zendy; Barthélémy Lucas | Zendy; Bourdreux Flavien | Zendy; Tuccio Béatrice | Zendy; Dagousset Guillaume | Zendy; Pégot Bruce | Zendy; Magnier Emmanuel | Zendy

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Visible‐Light‐Induced Metal‐Free Trifluoromethylselenolation of Electron‐Rich Heteroarenes Using the Nucleophilic [Me 4 N][SeCF 3 ] Reagent

Author(s) -

De ZordoBanliat Arnaud,

Barthélémy Lucas,

Bourdreux Flavien,

Tuccio Béatrice,

Dagousset Guillaume,

Pégot Bruce,

Magnier Emmanuel

Publication year - 2020

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201901793

Subject(s) - chemistry , regioselectivity , reagent , visible spectrum , surface modification , nucleophile , electron paramagnetic resonance , combinatorial chemistry , photochemistry , metal , photoredox catalysis , organic chemistry , photocatalysis , catalysis , optoelectronics , physics , nuclear magnetic resonance

A metal‐free visible‐light‐promoted regioselective trifluoromethylselenolation of electron‐rich heteroarenes has been developed using C–H functionalization. This eco‐friendly, atom‐economical, and easy‐to‐operate protocol provides direct access to a wide range of functionalized SeCF 3 ‐containing heteroarenes in high yields, and is amenable to continuous flow techniques. A radical mechanism was supported by EPR experiments.

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