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Front Cover: Chemoselective C–S/S–S Formation between Diaryl Disulfides and Tetraalkylthiuram Disulfides (Eur. J. Org. Chem. 47/2019)
Author(s) -
Peng Kang,
Zhu Hui,
Liu Xing,
Peng HanYing,
Chen JinQuan,
Dong ZhiBing
Publication year - 2019
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201901758
Subject(s) - chemistry , front cover , aryl , cover (algebra) , catalysis , base (topology) , combinatorial chemistry , polymer chemistry , medicinal chemistry , stereochemistry , organic chemistry , mechanical engineering , mathematical analysis , alkyl , mathematics , engineering
The Front Cover shows an efficient C–S/S–S formation for the chemo‐selective synthesis of aryl dithio‐carbamates and aryl dialkylcarbamo‐(dithioperoxo)thioates. The approach uses inexpensive and readily available diphenyl disulfides and tetramethyl thiuram disulfides as starting materials, a series of aryl dithiocarbamates and aryl dimethylcarbamo(dithioperoxo)thioates could be furnished smoothly in moderate to good yields by modulating the reaction temperature, base, and catalyst. The S–S bond formation was confirmed by X‐ray crystallography. More information can be found in the Full Paper by Z.‐B. Dong et al.