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Thioether‐Facilitated Iridium‐Catalyzed Hydrosilylation of Steric 1,1‐Disubstituted Olefins
Author(s) -
Zhang Xueyan,
Gao Chengpeng,
Xie Xingze,
Liu Yuanqi,
Ding Shengtao
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201901513
Subject(s) - hydrosilylation , thioether , chemistry , steric effects , iridium , organosilicon , catalysis , substrate (aquarium) , organic chemistry , combinatorial chemistry , polymer chemistry , oceanography , geology
One facile and efficient strategy for the hydrosilylation of steric 1,1‐disubstituted terminal alkenes is demonstrated. Investigations on substrate scope and control experiments revealed the necessity of thioether in promoting this process under a simple iridium catalytic system. This convenient and feasible method is expected to be useful in the synthesis of sulfur‐containing organosilicon polymers with different side‐chains.