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Probing the Effect of Counterions on the Oxidation of Alcohols Using Oxoammonium Salts
Author(s) -
Miller Shelli A.,
Nandi Jyoti,
Leadbeater Nicholas E.,
Eddy Nicholas A.
Publication year - 2020
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201901369
Subject(s) - counterion , chemistry , salt (chemistry) , hydrogen bond , organic chemistry , silver salts , ion , medicinal chemistry , molecule
The effect of varying the counterion in the oxoammonium salt mediated oxidation of alcohols has been probed. Computational and experimental results suggest that the counterion is non‐innocent in oxoammonium salt mediated oxidations and the outcome of the reaction is related, at least in part, to the ability of the hydrogen‐bond accepting nature of the anion.