Iodocarbocyclization to Access Six‐ and Seven‐Membered Phosphacycles from Phosphoryl‐Linked Alkynes | Zendy

Wu Di | Zendy; Hu Chaopeng | Zendy; Qiu Liqi | Zendy; Duan Zheng | Zendy; Mathey François | Zendy

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Iodocarbocyclization to Access Six‐ and Seven‐Membered Phosphacycles from Phosphoryl‐Linked Alkynes

Author(s) -

Wu Di,

Hu Chaopeng,

Qiu Liqi,

Duan Zheng,

Mathey François

Publication year - 2019

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201901165

Subject(s) - chemistry , alkyne , linker , conjugated system , stereochemistry , molecule , combinatorial chemistry , organic chemistry , polymer , catalysis , computer science , operating system

The iodocarbocyclization of the tethered alkyne is an important method for diverse family of cyclic molecules. Using the phosphoryl group as a new linker leads to the formation of α‐iodo‐substituted spiro‐conjugated phosphinoline and phosphepines, which were further transformed to π‐elongated derivatives and provided a phosphepine based aggregation‐induced emission (AIE) luminogen.

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