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Direct Azidation of Phenols
Author(s) -
Kitamura Mitsuru,
Murakami Kento,
Koga Tatsuya,
Eto Takashi,
Ishikawa Akihiro,
Shimooka Hirokazu,
Okauchi Tatsuo
Publication year - 2019
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201900967
Subject(s) - chemistry , phenols , phenol , sodium azide , amine gas treating , organic chemistry , azide , chloride
Direct azidation of phenols was developed. By treating chloroimidazolinium chloride 1b and sodium azide with phenol in the presence of a secondary amine in methoxyethanol, ortho ‐azidation of phenol was achieved.