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Direct Glycosidation of 2‐Azido‐2‐deoxyglycosyl Nitrates
Author(s) -
Singh Yashapal,
Wang Tinghua,
Demchenko Alexei V.
Publication year - 2019
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201900748
Subject(s) - chemistry , glycosyl , glycosylation , lanthanide , combinatorial chemistry , organic chemistry , stereochemistry , ion , biochemistry
Glycosyl nitrates are important synthetic intermediates which had never been glycosidated before our recent discovery that glycosyl nitrates can be glycosidated in the presence of lanthanides. Presented herein is our preliminary attempt to enhance the utility of glycosyl nitrates as donors for O ‐glycosidation of 2‐amino‐2‐deoxysugars.