B(C 6 F 5 ) 3 ‐Catalyzed Reduction of Cyclic  N ‐Sulfonyl Ketimines | Zendy

Shi Lei | Zendy; Bao Robert LiYuan | Zendy; Zheng Limin | Zendy; Zhao Rong | Zendy

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B(C 6 F 5 ) 3 ‐Catalyzed Reduction of Cyclic N ‐Sulfonyl Ketimines

Author(s) -

Shi Lei,

Bao Robert LiYuan,

Zheng Limin,

Zhao Rong

Publication year - 2019

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201900706

Subject(s) - chemistry , sulfonyl , reagent , catalysis , reduction (mathematics) , medicinal chemistry , combinatorial chemistry , functional group , organic chemistry , alkyl , geometry , mathematics , polymer

A metal‐free method for reduction of cyclic N ‐sulfonyl ketimines catalyzed by B(C 6 F 5 ) 3 , using commercially available methylphenylsilane as a reducing reagent under mild conditions has been developed. This reductive protocol was effective, not only providing the expected cyclic N ‐sulfonamides in good to excellent yields, but also showing good functional‐group tolerance.

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