New Geometries for Calix[6]arene‐Based Rotaxanes | Zendy

Bazzoni Margherita | Zendy; Zanichelli Valeria | Zendy; Casimiro Lorenzo | Zendy; Massera Chiara | Zendy; Credi Alberto | Zendy; Secchi Andrea | Zendy; Silvi Serena | Zendy; Arduini Arturo | Zendy

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New Geometries for Calix[6]arene‐Based Rotaxanes

Author(s) -

Bazzoni Margherita,

Zanichelli Valeria,

Casimiro Lorenzo,

Massera Chiara,

Credi Alberto,

Secchi Andrea,

Silvi Serena,

Arduini Arturo

Publication year - 2019

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201900211

Subject(s) - chemistry , calixarene , stereochemistry , solid state , rotaxane , characterization (materials science) , derivative (finance) , redox , supramolecular chemistry , combinatorial chemistry , crystallography , nanotechnology , molecule , crystal structure , organic chemistry , materials science , financial economics , economics

Understanding the role played by the nature, number, and arrangement of binding sites anchored to a macrocycle remains a topic of current interest for the synthesis of new interwoven species. We report the synthesis and detailed structural characterization of a new calix[6]arene derivative decorated with two phenylureido groups anchored at the diametrical position of the calix upper rim that adopts a 1,2,3‐alternate conformation in solution and in the solid state. Preliminary data on the ability of this host to form redox‐active pseudorotaxanes and rotaxanes are reported.

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