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Front Cover: Diverse Multi‐Functionalized Oligoarenes and Heteroarenes for Porous Crystalline Materials (Eur. J. Org. Chem. 7/2019)
Author(s) -
Grosjean Sylvain,
Hassan Zahid,
Wöll Christof,
Bräse Stefan
Publication year - 2019
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201900166
Subject(s) - borylation , front cover , chemistry , terphenyl , biphenyl , pyridine , molecular engineering , alkyne , porosity , palladium , polymer chemistry , cover (algebra) , combinatorial chemistry , nanotechnology , organic chemistry , catalysis , materials science , aryl , mechanical engineering , alkyl , engineering
The Front Cover shows the molecular architecture of SURMOFs assembled in a layer‐by‐layer fashion from multi‐functionalized (azide, hydroxy, alkyne, etc.) biphenyl, terphenyl, and higher linear oligophenylene dicarboxylic acids and pyridine‐terminated oligoarenes. Their modular synthesis was achieved by stepwise palladium‐catalyzed borylation / Suzuki–Miyaura cross‐coupling reactions. These ditopic organic linkers are ideally suited as molecular bricks in the construction of complex, porous, and multifunctional crystalline designer materials. More information can be found in the Full Paper by S. Bräse et al.